Thermal, photochemical and electrochemical reactions on dinuclear platinum(III) complexes by Samuel A. Bryan

Cover of: Thermal, photochemical and electrochemical reactions on dinuclear platinum(III) complexes | Samuel A. Bryan

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Written in English

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Subjects:

  • Platinum compounds.,
  • Platinum group -- Analysis.,
  • Chemical reactions.

Edition Notes

Book details

Statementby Samuel A. Bryan.
The Physical Object
Paginationx, 142 leaves, bound :
Number of Pages142
ID Numbers
Open LibraryOL16972312M

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On the other hand, energy conversion by photochemical system is not subject to this limitation unless the thermal reactions are included in the cycle. Many hydrogen or oxygen producing reactions are found in both thermochemical and photochemical cases; however, only a few of them lead to complete closed cycles of water decomposition.

Thermal and Photochemical Silicon−Carbon Bond Activation in Donor-Stabilized Platinum(0)−Alkyne Complexes Christian Müller, Rene J. Lachicotte, and William D. Jones * Department of Chemistry, University of Rochester, Rochester, New York Structural and Photochemical Properties of Organosilver Reactive Intermediates MeAg2+ and PhAg2+ Article in The Journal of Physical Chemistry A (33) August with 38 Reads.

Cart ACS; ACS Publications; C&EN; CAS; ACS Journals. Samuel A. Bryan has written: 'Thermal, photochemical and electrochemical reactions on dinuclear platinum(III) complexes' -- subject(s): Chemical reactions, Platinum compounds, Analysis, Platinum. Modulation of the Photophysical, Photochemical, and Electrochemical Properties of Re(I) Diimine Complexes by Interligand InteractionsCited by: 7.

Cover Picture: Chemical, Electrochemical, and Photochemical Catalytic Oxidation of Water to Dioxygen with Mononuclear Ruthenium Complexes (ChemSusChem 2/). Dinuclear Nickel Complexes of Thiolate-Functionalized Carbene Ligands and Their Electrochemical PropertiesCited by: 4.

Photoinduced Multielectron Redox Reactions in the [PtCl 6] 2-/Alcohol System: Visible Light Reduction of Platinum Centers, Proceedings of the Seventh International Symposium on the Photochemistry and Photophysics of Coordination Compounds; Vogler, A., Yersin, H. Methods and systems for heterocycle catalyzed carbonylation and hydroformylation with carbon dioxide are disclosed.

A method may include, but is not limited to, steps (A) to (D). Step (A) may introduce water to a first compartment of an electrochemical cell. The first compartment may include an anode. Step (B) may introduce carbon dioxide to a second compartment of the electrochemical cell.

Ruthenium trichloride and various ruthenium complexes have been reported to catalyse olefin polymerization; some results are shown in Table particular interest are the ring-opening polymerization of strained or small ring olefins, such as norbornene, cyclobutene and cyclopentene, which can be regarded as metathesis reactions.

Herein, we present dinuclear complexes incorporating a 2,5-di-(2-pyridyl)pyrazine ligand. The properties for these complexes are contrasted with mononuclear model systems.

Electrochemical and photochemical properties will be discussed and these results will be compared to DFT studies. a =abstract Page; Book Review, Physical Metallurgy of the Platinum Metals: Temperature Measurement Catalysts, continuous photochemical and electrochemical reactions on dinuclear platinum book of: 2: polymetallic cluster: Iridium, IrCl 3, H 2 transfer from amines to olefins over, a: IrCl 3, reactions of amines with buta-1, 3-diene and isoprene in the presence of, a: complexes, trans-IrCl(CO)(PPh 3) 2, conversion of acyl.

Photochemical, Electrochemical, and Photochemistry of a Dinuclear Cyanide-Bridged Iron(II)-Platinum(IV) Mixed-Valence Compound and Its Implications for the Corresponding Iron(II)-Platinum(IV)-Iron(II) Complex.

The Design of Reagents Thermal Photochemical and Thermal Multiple Electron Transfer Reactions Comments On Inorganic Chemistry. "Reactive Intermediates in the Thermal and Photochemical Reactions of Trinuclear Ruthenium Carbonyl Clusters", P.C.

Ford, A.E. Friedman and D.J. Taube, ACS Symposium Series,(). "The Photoisomerization of the Ruthenium Cluster HRu3(CO)10(m-COCH3)", A.E. Friedman and P.C. Ford in "Photophysics and Photochemistry of Coordination. Derek A. Tocher and Joanne H.

Tocher, Electrochemical and spectroelectrochemical studies on three dinuclear rhodium(II) complexes with O-oxypyridine anions as ligands, Inorganica Chimica Acta,1, Cited by: Photochemical reactions of diiron μ̀-alkenylidene complexes with hydrogen, trialkylsilanes, and diazo compounds: Cleavage to alkenes, vinylsilanes, and allenes Journal of the American Chemical Society.

1: Casey CP, Smith LJ. Classes of reactions include ligand substitutions, redox reactions, electron transfer reactions, reactions within the coordination sphere of metal ions including catalysis by.

Thermal and Photochemical Reactivity of Manganese Tricarbonyl and Tetraarbonyl Complexes with a Bulky Diazabutadiene Ligand. Book Review of Poly(Lactic Acid): Synthesis, Structures, Properties, Processing, Photochemical Reactions of Transition Metal Dinitrogen Compounds in the Presence of Carbon Monoxide.

A comprehensive book that explores nitrogen fixation by using transition metal-dinitrogen complexes Nitrogen fixation is one of the most prominent fields of research in chemistry. This book puts the focus on the development of catalytic ammonia formation from nitrogen gas under ambient reaction conditions that has been recently repowered by some research groups.

With contributions from noted Author: Yoshiaki Nishibayashi. As depicted in Figure 3, a broad number of substrates can be reduced using [(NN)Rh(Cp*)X] n +-like structures as catalysts by means of chemical, electrochemical, or photochemical methods. In addition, imines [ 26, 27, 28 ] and α,β-unsaturated carbonyl compounds [ 29 ] can also be reduced with this type of catalyst, as well as nitrogen Cited by: 3.

Macrocyclic compounds that can bind cationic species efficiently and selectively with their cyclic cavities have great potential as excellent chemosensors for metal ions.

Recently, we have developed a tetraoxime-type tetraazamacrocyclic ligand 1 formed through a facile one-pot cyclization reaction. Aiming to explore and bring out the potential of the tetraoxime macrocycle 1 as a chelating Cited by: 4. The direct correlation between gas‐phase and solid‐state supramolecular structures of massive protein‐sized polyoxometalate clusters (ca.

21 kDa) has been probed using cryospray mass spectrometry. In their Communication on page ff., L. Cronin et al. show that such clusters can be crystallized into the solid state, and their macromolecular structure controlled, thus allowing the.

Department of Biology, Chemistry, Pharmacy / Chemistry and Biochemistry / Chemistry / Sarkar Group. Menu. Prof. Biprajit Sarkar A combined thermal, electrochemical and photochemical case study with a click tripodal ligand.” J.

Klein, U. Albold, L. Suntrup and B. Sarkar*, “Redox Behavior of a Dinuclear Ruthenium(II) Complex Bearing. Mass transport is much more likely to be rate-controlling in the heterogeneous catalysis of solution reactions than in that of gas reactions.

The reason lies in the magnitudes of the respective diffusion coefficients [48]:for molecules in normal gases at 1 bar and K these are to m'5-l while, for typical solutes in aqueous solution, they are.

Methods and systems for electrochemical reduction of carbon dioxide using advanced aromatic amine heterocyclic catalysts are disclosed.

A method for electrochemical reduction of carbon dioxide may include, but is not limited to, steps (A) to (C). Step (A) may introduce water to a first compartment of an electrochemical cell. The first compartment may include an by: 8.

The present disclosure generally relates to the field of electrochemical reactions, and more particularly to advanced aromatic amine heterocyclic catalysts for carbon dioxide reduction. BACKGROUND The combustion of fossil fuels in activities such as electricity generation, transportation, and manufacturing produces billions of tons of carbon.

Artificial photosynthesis is a chemical process that biomimics the natural process of photosynthesis to convert sunlight, water, and carbon dioxide into carbohydrates and term artificial photosynthesis is commonly used to refer to any scheme for capturing and storing the energy from sunlight in the chemical bonds of a fuel (a solar fuel).

de Tacconi, R. Lezna, R. Konduri, F. Ongeri, K. Rajeshwar and F. Macdonnell, “Influence of pH on the Photochemical and Electrochemical Reduction of the Dinuclear Ruthenium Complex, [(phen)2Ru(tatp)Ru(phen)2]Cl4, in Water: Proton-Coupled Sequential and Concertad Multi-Electron Reduction,” Chemistry Eur.

Issues in Chemistry and General Chemical Research: Edition is a ScholarlyEditions™ eBook that delivers timely, authoritative, and comprehensive information about Chemistry and General Chemical Research. The editors have built Issues in Chemistry and General Chemical Research: Edition on the vast information databases of ScholarlyNews.™ You can expect the information about 3/5(2).

Comprehensive Coordination Chemistry II (CCC II) is the sequel to what has become a classic in the field, Comprehensive Coordination Chemistry, published in CCC II builds on the first and surveys new developments authoritatively in over newly comissioned chapters, with an emphasis on current trends in biology, materials science and other areas of contemporary scientific interest.

W.W. Frese, Jr., Electrochemical and Electrocatalytic Reactions of Carbon Dioxide—Chapter 6: Electrochemical Reduction of CO2 at Solid Electrodes, Elsevier, Amsterdam,pp. Halmann and Steinberg, Greenhouse gas carbon dioxide mitigation: science and technology—Chapter Photochemical and Radiation-Induced Activation of CO2.

Electrochemical control of polymer solubility is a current issue, with applications in smart colloids, gels, and self-assembled systems. Electrode modification is addressed briefly.

Different stimuli-responsive systems are categorized by highlighting the peculiarity of electrochemical by: Reviews, Book Chapters, Commentary, Book editing etc. J.J. Vittal and M.T. Ng, “Chemistry of Metal Thio- and Selenocarboxylates – Precursors for Metal Sulfide/Selenide Materials, Thin Films and Nanocrystals,” Accounts of Chemical Research (submitted an invited review).

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They are mainly based on platinum complexes (mono- and binuclear) with a nitrogen rich coordination sphere. Binuclear Pt hydrogen evolving catalysts Co catalysts Cobalt complexes stabilised by other remarkable stability in water nitrogen donor ligands have high activity in both photochemical and electrochemical systems.

Newly developed “one point touch” DEMS (Differential Electrochemical Mass Spectrometer) was applied to a small Pt single crystal electrode of ca. cm 2 and succeeded to follow the electrode reactions of NO 2 − in situ, together with voltammogram at a potential sweep of 2–10 mVs −1.

Methods for electrochemical production of formic acid are disclosed. A method may include, but is not limited to, steps (A) to (D). Step (A) may introduce water to a first compartment of an electrochemical cell. The first compartment may include an anode. Step (B) may introduce carbon dioxide to a second compartment of the electrochemical by: Full text of "CRC Handbook of Organic Photochemistry and Photobiology" See other formats.

Full text of "Encyclopedia of Electrochemistry" See other formats. “Photochemical reactions of metal complexes in the solid state,” J.J. Vittal, H.S “Reversible Single-Crystal-to-Single-Crystal Photochemical Formation and Thermal Cleavage of a Cyclobutane Ring” G.K. Kole, T.

Kojima, M. Kawano, J.J. Vittal, “Electronic interactions in dinuclear platinum, palladium ethynylferrocene File Size: KB.Rh(I) Subsititution Reactions" Inorg.

Chem, () Zhenyang Lin and Michael B. Hall* "Hydride locations and bonding studies in some silyl polyhydride rhenium complexes" Inorg. Chem, () Zhenyang Lin and Michael B. Hall* "Closed-shell electronic structures for linear L n MXML n dinuclear transition.Metal–organic frameworks (MOFs) are a class of compounds consisting of metal ions or clusters coordinated to organic ligands to form one- two- or three-dimensional structures.

They are a subclass of coordination polymers, with the special feature that they are often organic ligands included are sometimes referred to as "struts", one example being 1,4-benzenedicarboxylic acid (BDC).

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